P-CUMYLPHENYL METHACRYLATE - SYNTHESIS, POLYMERIZATION, AND COPOLYMERIZATION

Authors
BINDUSHREE CV VENKATARAMANAN B KHISTI RS SIVARAM S
Citation
Cv. Bindushree et al., P-CUMYLPHENYL METHACRYLATE - SYNTHESIS, POLYMERIZATION, AND COPOLYMERIZATION, Journal of macromolecular science. Pure and applied chemistry, A35(1), 1998, pp. 183-191
Citations number
8
Categorie Soggetti
Polymer Sciences
Journal title
Journal of macromolecular science. Pure and applied chemistry → ACNP
ISSN journal
10601325
Volume
A35
Issue
1
Year of publication
1998
Pages
183 - 191
Database
ISI
SICI code
1060-1325(1998)A35:1<183:PM-SPA>2.0.ZU;2-N
Abstract
A new methacrylic monomer from the reaction of methacryloyl chloride w ith p-cumylphenol has been synthesized. The effect of sterically bulky p-cumylphenyl group on homopolymerization and copolymerization was ex amined. In copolymers, p-cumylphenyl methacrylate increases the T-g of acrylic polymers. The T-g of the copolymers as determined by DSC agre es with both the Flory-Fox and Gordon-Taylor relationships.