Grain boundary character distribution is a relatively new microstructu
ral feature that describes the proportions of random and special grain
boundaries as defined by the coincident site lattice model. The combi
nation of the availability of a new experimental technique based on th
e automatic indexing of backscatter Kikuchi electron diffraction patte
rns in the scanning electron microscope (orientation imaging microscop
y) and reports in the literature describing the optimization of the gr
ain boundary character distribution through thermomechanical processin
g are making the potential for enhanced materials properties in commer
cial metals and alloys a reality. Although the effects of optimizing t
he grain boundary character distribution in the cost-effective improve
ment of properties have been documented, the potential for commerciali
zation has limited the disclosure of processing details. In this artic
le, two separate approaches to the optimization of the grain boundary
character distribution in oxygen-free electron copper at Lawrence Live
rmore National Laboratory are discussed.