YDROXYPHENYLBENZTHIAZOLATO-NITROSYL-MOLYBDENUM(II) - A CHELATE WHICH SIMULTANEOUSLY CONTAINS AN AZOMETHINE LIGAND AND ITS CYCLIC OXIDATION-PRODUCT

Authors
BANSSE W FLIEGNER J SAWUSCH S SCHILDE U UHLEMANN E
Citation
W. Bansse et al., YDROXYPHENYLBENZTHIAZOLATO-NITROSYL-MOLYBDENUM(II) - A CHELATE WHICH SIMULTANEOUSLY CONTAINS AN AZOMETHINE LIGAND AND ITS CYCLIC OXIDATION-PRODUCT, Inorganica Chimica Acta, 269(2), 1998, pp. 350-352
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganica Chimica Acta → ACNP
ISSN journal
00201693
Volume
269
Issue
2
Year of publication
1998
Pages
350 - 352
Database
ISI
SICI code
0020-1693(1998)269:2<350:Y-ACWS>2.0.ZU;2-V
Abstract
ydroxyphenylbenzthiazolato-nitrosyl-molybdenum(II) was synthesized by ligand exchange reaction of Mo(NO)(2)acac(2) with salicylaldehyde-2-me rcaptoanil. Besides the starting ligand the complex likewise contains the cyclic oxidation product. The compound crystallizes in the monocli nic space group P2(1)/n (No. 14) with a = 11.026(9), b = 9.228(3), c = 23.883(10) Angstrom, beta = 102.23(5)degrees, V = 2375 Angstrom x(3). (C) 1998 Elsevier Science S.A.