T. Hertel et al., MANIPULATION OF INDIVIDUAL CARBON NANOTUBES AND THEIR INTERACTION WITH SURFACES, JOURNAL OF PHYSICAL CHEMISTRY B, 102(6), 1998, pp. 910-915
We demonstrate that the tip of an atomic force microscope (AFM) can be
used to control the shape and position of individual multiwalled carb
on nanotubes dispersed on a surface. Specifically we can bend, straigh
ten, translate. rotate, and-under certain conditions-cut nanotubes. Su
ch manipulations are feasible due to the interaction between nanotubes
and the substrate, which can stabilize highly strained nanotube confi
gurations. Direct evidence for this interaction is provided by the stu
dy of elastic distortions of tubes interacting with other tubes and th
e substrate, From the observed deformations of nanotubes with 100 Angs
trom diameter. For example, we obtain a binding energy of 0.8 +/- 0.3
eV/Angstrom. This interaction forces nanotubes to conform to the struc
ture of the substrate, and the resulting distortions should induce cor
responding changes in their electronic structure and electrical transp
ort properties.