EPR STUDIES OF VO2-DOT-3H(2)O SINGLE-CRYSTALS( IN BA(CLO4)(2)CENTER)

Citation
M. Yavuz et al., EPR STUDIES OF VO2-DOT-3H(2)O SINGLE-CRYSTALS( IN BA(CLO4)(2)CENTER), Zeitschrift fur Naturforschung. A, A journal of physical sciences, 52(12), 1997, pp. 849-854
Citations number
26
ISSN journal
09320784
Volume
52
Issue
12
Year of publication
1997
Pages
849 - 854
Database
ISI
SICI code
0932-0784(1997)52:12<849:ESOVSI>2.0.ZU;2-N
Abstract
The results of an electron paramagnetic resonance (EPR) study of vanad yl ion VO2+ doped in single crystals of Ba (ClO4)(2) . 3H(2)O are repo rted. The spectra indicated the presence of two substitutional and int erstitial sites depending on the orientation. The spin-Hamiltonian par ameters were determined from single crystal and powder EPR data. These parameters were found to be axial symmetric for the powder sample, wh ereas they showed deviations from axial symmetry for the single crysta l.