ENANTIOSELECTIVE HYDROFORMYLATION OF OLEFINS CATALYZED BY RHODIUM(I) COMPLEXES OF CHIRAL PHOSPHINE-PHOSPHITE LIGANDS

Authors
NOZAKI K TAKAYA H HIYAMA T
Citation
K. Nozaki et al., ENANTIOSELECTIVE HYDROFORMYLATION OF OLEFINS CATALYZED BY RHODIUM(I) COMPLEXES OF CHIRAL PHOSPHINE-PHOSPHITE LIGANDS, Topics in catalysis, 4(3-4), 1997, pp. 175-185
Citations number
55
Journal title
Topics in catalysis → ACNP
ISSN journal
10225528
Volume
4
Issue
3-4
Year of publication
1997
Pages
175 - 185
Database
ISI
SICI code
1022-5528(1997)4:3-4<175:EHOOCB>2.0.ZU;2-J
Abstract
Using Rh(I) complexes of chiral phosphine-phosphites, hydroformylation of such a variety of olefins as aryl-substituted, alkyl-substituted, and heteroatom-substituted ones proceeded in high enantioselectivity. A trigonal bipyramidal RhH(CO)(2)(phosphine-phosphite) complex is sugg ested as the active species, in which the hydride and the phosphite mo iety are located at the apical positions.