The influence of sulphidation treatment on the performance of room tem
perature InAsPSb/InAs photodetectors was investigated. Measurements of
photoresponsivity, external quantum efficiency and detectivity of the
detectors with and without the sulphidation treatment showed that aft
er the sulphidation treatment the sensitivity of the detectors improve
d 1.5 times. A study of the chemical state of sulphur on an (NH4)(2)S-
x-treated InAs(001) surface was performed by high-resolution X-ray pho
toelectron spectroscopy (XPS). The chemical state of sulphur bonded to
indium (In) and arsenic (As) atoms for the as-treated surface was obs
erved showing the termination of the dangling bonds at the surface by
the sulphidation treatment. This gives rise to a remarkable decrease o
f surface recombination center density and results in the increase of
photodetector sensitivity.