ITA
ENG

THE PREPARATION OF (E)-1-ALKENYLTHIOSILANES BY THE REDUCTION AND SILICON CAPTURE OF 1-ALKENESULFENATE ANIONS

Authors

SCHWAN AL REFVIK MD

Citation

Al. Schwan et Md. Refvik, THE PREPARATION OF (E)-1-ALKENYLTHIOSILANES BY THE REDUCTION AND SILICON CAPTURE OF 1-ALKENESULFENATE ANIONS, Synlett, (1), 1998, pp. 96

Citations number

Categorie Soggetti

Chemistry Inorganic & Nuclear

Journal title

Synlett → ACNP

ISSN journal

09365214

Issue

Year of publication

1998

Database

ISI

SICI code

0936-5214(1998):1<96:TPO(BT>2.0.ZU;2-5

Abstract

A collection of (E)-1-alkenesulfenate anions were reduced by LiAlH4 at law temperature. The resulting enethiolates, with their E geometry in tact, could be captured with chlorosilane to afford silicon protected enethiol ethers of thioaldehydes and thioketones. Reduction at a highe r temperature prompts isomerization of the double bond.