Time of flight secondary ion mass spectroscopy is a new technique for
probing the chemistry of surfaces. Applying the technique to many pape
rs and papermaking problems shows that it its a powerful tool for anal
ysis and problem solving. The authors discuss various applications in
detail with emphasis on problems involving defects and runnability. Th
e technique helped resolve a sizing problem where pitch was a highly e
ffective desizing agent. This brought new insight to an old problem-wh
y some pulps are more difficult to size than others.