AXIALLY CHIRAL DILACTAMS - SYNTHESIS, RACEMIZATION BARRIERS AND CRYSTAL-STRUCTURES

Authors
TICHY M RIDVAN L HOLY P ZAVADA J CISAROVA I PODLAHA J
Citation
M. Tichy et al., AXIALLY CHIRAL DILACTAMS - SYNTHESIS, RACEMIZATION BARRIERS AND CRYSTAL-STRUCTURES, Tetrahedron : asymmetry, 9(2), 1998, pp. 227-234
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
9
Issue
2
Year of publication
1998
Pages
227 - 234
Database
ISI
SICI code
0957-4166(1998)9:2<227:ACD-SR>2.0.ZU;2-Q
Abstract
The racemic as well as optically active dilactams 1 and 2 were prepare d as the first representatives of axially chiral dilactams possessing a biaryl axis as the sole element of chirality. Their absolute configu rations and inversion barriers were determined. The molecular structur e and supramolecular self-assembly of the racemic dilactams directed b y hydrogen bonding and aryl-aryl stacking was elucidated by single cry stal diffraction analysis. (C) 1998 Elsevier Science Ltd. All rights r eserved.