EITHER GAMMA-SYN-SELECTIVE OR GAMMA-ANTI-SELECTIVE PALLADIUM-CATALYZED CARBONYL ALLYLATION BY MIXED (E)-1,3-DICHLOROPROPENE AND (Z)-1,3-DICHLOROPROPENE WITH TIN(II) HALIDES

Authors
MASUYAMA Y ITO A KURUSU Y
Citation
Y. Masuyama et al., EITHER GAMMA-SYN-SELECTIVE OR GAMMA-ANTI-SELECTIVE PALLADIUM-CATALYZED CARBONYL ALLYLATION BY MIXED (E)-1,3-DICHLOROPROPENE AND (Z)-1,3-DICHLOROPROPENE WITH TIN(II) HALIDES, Chemical communications, (3), 1998, pp. 315-316
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
3
Year of publication
1998
Pages
315 - 316
Database
ISI
SICI code
1359-7345(1998):3<315:EGOGP>2.0.ZU;2-R
Abstract
Palladium-catalysed carbonyl allylations by mixed (E)- and (Z)-1,3-dic hloropropene with SnI2-Bu4NI and SnCI2 diastereoselectively produce sy n and anti 1-substituted 2-chlorobut-3-en-1-ols, respectively. These a re transformed into cis and trans 1-substituted 2-vinyl epoxides.