INTERMOLECULAR HYDROGEN-CENTER-DOT-CENTER-DOT-CENTER-DOT-METAL INTERACTIONS - THE CRYSTAL-STRUCTURE OF (CIS-[PDCL2(TPA)(2)])2-CENTER-DOT-H2O, A WATER-SOLUBLE PALLADIUM(II) TERTIARY PHOSPHINE COMPLEX

Authors
ALYEA EC FERGUSON G KANNAN S
Citation
Ec. Alyea et al., INTERMOLECULAR HYDROGEN-CENTER-DOT-CENTER-DOT-CENTER-DOT-METAL INTERACTIONS - THE CRYSTAL-STRUCTURE OF (CIS-[PDCL2(TPA)(2)])2-CENTER-DOT-H2O, A WATER-SOLUBLE PALLADIUM(II) TERTIARY PHOSPHINE COMPLEX, Chemical communications, (3), 1998, pp. 345-346
Citations number
34
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
3
Year of publication
1998
Pages
345 - 346
Database
ISI
SICI code
1359-7345(1998):3<345:IHI>2.0.ZU;2-9
Abstract
The single-crystal X-ray structural determination of {cis-[PdCl2(TPA)( 2)]}(2) . H2O (TPA = 1,3,5-triaza-7-phosphaadamantane) establishes tha t pairs of cis-[PdCl2(TPA)(2)] molecules are linked about inversion ce ntres by intermolecular Pd ... H ... C three-centre-four-electron inte ractions (2.86, 3.00 Angstrom for the two independent dimers); the wat er molecule links these dimers via O-H ... N hydrogen bonds to form in finite chains extending in the c-direction in the crystal lattice.