SULFINYL VERSUS ALLYLIC STEREOCONTROL IN DIELS-ALDER CYCLOADDITIONS OF HYDROXY 2-SULFINYL BUTADIENES

Authors
DELAPRADILLA RF MONTERO C VISO A
Citation
Rf. Delapradilla et al., SULFINYL VERSUS ALLYLIC STEREOCONTROL IN DIELS-ALDER CYCLOADDITIONS OF HYDROXY 2-SULFINYL BUTADIENES, Chemical communications, (3), 1998, pp. 409-410
Citations number
28
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
3
Year of publication
1998
Pages
409 - 410
Database
ISI
SICI code
1359-7345(1998):3<409:SVASID>2.0.ZU;2-3
Abstract
Enantiopure hydroxy 2-sulfinyl butadienes undergo a highly face select ive Diels-Alder cycloaddition with N-phenylmaleimide and phenyltriazol inedione controlled by the chiral sulfur atom; the related enantiopure sulfonyl dienes display complimentary pi-facial selectivity.