TRIPHENYLPHOSPHINE-P)-ARACHNO-6-THIADECABORANE(11) TRICHLOROMETHANE (1 1)/

Authors
COOKE PA HOLUB J KENNEDY JD STIBR B THORNTONPETT M
Citation
Pa. Cooke et al., TRIPHENYLPHOSPHINE-P)-ARACHNO-6-THIADECABORANE(11) TRICHLOROMETHANE (1 1)/, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 121-123
Citations number
21
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
1
Pages
121 - 123
Database
ISI
SICI code
0108-2701(1998)54:<121:TT(>2.0.ZU;2-4
Abstract
The title compound, C18H26B9PS.CHCl3 is shown to have an arachno ten-v ertex {6-SB9H11} cluster structure with a PPh3 ligand in the exo-9-pos ition. The two bridging H atoms occupy asymmetric positions [average B -H-bridge values 1.21(4) and 1.35(4) Angstrom] displaced away from the S atom.