2-(5-CHLORO-2-NITROPHENYLTHIO)NICOTINOYL CHLORIDE

Authors
GARCIA JG HAYDAR SH KRAPCHO AP LIU YH FRONCZEK FR
Citation
Jg. Garcia et al., 2-(5-CHLORO-2-NITROPHENYLTHIO)NICOTINOYL CHLORIDE, Acta crystallographica. Section C, Crystal structure communications, 54, 1998, pp. 146-148
Citations number
16
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
54
Year of publication
1998
Part
1
Pages
146 - 148
Database
ISI
SICI code
0108-2701(1998)54:<146:2C>2.0.ZU;2-K
Abstract
The two aromatic rings in the title compound, C12H6Cl2N2O3S, form a di hedral angle of 56.7(1)degrees. The alkanoyl chloride group lies sligh tly out of the plane of the aromatic ring with the carbonyl O and alka noyl Cl atoms lying 0.219(2) and -0.374(1) Angstrom, respectively, fro m the ring. The nitro group deviates from coplanarity with its aromati c ring, displaying a torsion angle along N-C of 34.9(3)degrees. The C- S-C angle is 102.85(9)degrees. Bond distances C=O and S-C have values of 1.178(3) Angstrom, and 1.766(2) and 1.767(2) Angstrom, respectively .