The synthesis of several highly phenylated poly(p-phenylenevinylene) (
PPV) derivatives by a chlorine precursor route was investigated in ord
er to understand its scope. Three 1,4-bis(chloromethyl)benzene monomer
s were prepared via a robust and versatile synthetic procedure involvi
ng the Diels-Alder reaction. In the presence of 1.1 equiv of potassium
tert-butoxide, the monomers underwent 1,6-dehydrochlorination to form
the respective xylylenes which underwent 1,6-polymerization to give t
he corresponding chlorine precursor polymers. The 1,6-polymerization m
echanism of the highly phenylated monomers is discussed. Only one mono
mer gave a soluble precursor polymer while the other two gave insolubl
e precursor polymers. The soluble precursor polymer was deposited as t
hin films and then converted to the corresponding PPV derivative, whic
h showed green photoluminesence and electroluminesence.