A. Sano et al., THEORY OF HIGH-TEMPERATURE SUPERCONDUCTIVITY IN CUPRATES - II - ELECTRON-SPIN COUPLED-STATE IN THE SUPERCONDUCTING CONCENTRATION REGION, International journal of modern physics b, 11(32), 1997, pp. 3751-3758
A new theoretical explanation is given for the superconducting state i
n copper oxides, based on the first principles variational calculation
for CuO6 octahedron and CuO5 pyramid. The key feature of the state is
the following: A coherent motion of itinerant holes due to the altern
ant appearance of low-spin and high-spin states in the presence of a l
ocal antiferromagnetic (AF) ordering of the Cu localized spins creates
a metallic and superconducting state. This theoretical prediction is
supported by very recent neutron inelastic scattering experiments by t
wo groups. On the basis of this new metallic state, the temperature ve
rsus hole concentration phase diagram is formed, and, based on this di
agram, the openings of the spin gap and a new normal-state energy gap
are discussed.