SYNTHESIS OF THE C(19)C(32) FRAGMENT OF SCYTOPHYCIN-C VIA STEREOSPECIFIC METHYLATION OF GAMMA,DELTA-EPOXY ACRYLATES WITH TRIMETHYLALUMINUM

Authors
GRIECO PA SPEAKE JD YEO SK MIYASHITA M
Citation
Pa. Grieco et al., SYNTHESIS OF THE C(19)C(32) FRAGMENT OF SCYTOPHYCIN-C VIA STEREOSPECIFIC METHYLATION OF GAMMA,DELTA-EPOXY ACRYLATES WITH TRIMETHYLALUMINUM, Tetrahedron letters, 39(10), 1998, pp. 1125-1128
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
10
Year of publication
1998
Pages
1125 - 1128
Database
ISI
SICI code
0040-4039(1998)39:10<1125:SOTCFO>2.0.ZU;2-F
Abstract
The synthesis of the C(19) - C(32) fragment of Scytophycin C is descri bed which features an iterative, stereospecific methylation of gamma,d elta-epoxy acrylates by trimethylaluminum and the use of Roush's (S,S) -diisopropyltartrate-E-crotylboronate. (C) 1998 Elsevier Science Ltd. All rights reserved.