THE CARBONYL-DIELS-ALDER REACTION CATALYZED BY BISMUTH(III) CHLORIDE

Authors
ROBERT H GARRIGUES B DUBAC J
Citation
H. Robert et al., THE CARBONYL-DIELS-ALDER REACTION CATALYZED BY BISMUTH(III) CHLORIDE, Tetrahedron letters, 39(10), 1998, pp. 1161-1164
Citations number
44
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
39
Issue
10
Year of publication
1998
Pages
1161 - 1164
Database
ISI
SICI code
0040-4039(1998)39:10<1161:TCRCBB>2.0.ZU;2-D
Abstract
In presence of bismuth (III) chloride, a carbonylated electrophile (et hyl mesoxalate or glyoxylate) and usual diene led selectively (65 to 1 00%) the hetero carbonyl-Diels-Alder reaction with the ene reaction pr oduct. BiCl3 exhibits strong catalytic activity and, compared with pre vious literature, reacts under mild conditions. (C) 1998 Elsevier Scie nce Ltd. All rights reserved.