In the present paper the results of measurements of carbon diffusion c
oefficients in Fe-C-Cr-Mn-Si steels are reported. The diffusion anneal
s were carried out at temperatures 900-1100 degrees C in ambient air.
The measurement of carbon concentration in subsurface layers of oxidiz
ed samples and the metallographic investigation have shown that the st
eels expressively decarburize in the course of oxidation. The evaluati
on of measured carbon concentration curves N(x,t) yielded the diffusio
n coefficients D of carbon. They depend on temperature T and on chemic
al composition of steels. The dependence of D on the concentration of
alloying elements i is expressed by the use of diffusion interaction c
oefficients beta(C)(i).