NAZR6CL10.94I3.06B - A 2ND STRUCTURE TYPE IN THE ZR(6)X(14)Z-FAMILY OF REDUCED ZIRCONIUM HALIDES - PERSPECTIVES FOR AN EVEN LARGER CLUSTER CHEMISTRY

Authors
KOCKERLING M
Citation
M. Kockerling, NAZR6CL10.94I3.06B - A 2ND STRUCTURE TYPE IN THE ZR(6)X(14)Z-FAMILY OF REDUCED ZIRCONIUM HALIDES - PERSPECTIVES FOR AN EVEN LARGER CLUSTER CHEMISTRY, Inorganic chemistry, 37(3), 1998, pp. 380
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
3
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:3<380:N-A2ST>2.0.ZU;2-S
Abstract
The mixed-halide cluster phase NaZr6Cl10.94I3.06B is the first compoun d within the reduced zirconium halides which has a structure that seem s to require two differently sized halide types. The three-dimensional connectivity of the Zr6X12B units (X = Cl, I) is achieved by exo iodi de ions which all bridge three different cluster units simultaneously.