BINUCLEAR AROYL AND CARBAMOYL COMPLEXES OF IRON - X-RAY CRYSTAL-STRUCTURES OF [FE-2(MU-SIGMA,SIGMA'-OCR)(2)(CO)(5)(PPH3)] (R = C6H3ME2-2,6,(NPR2)-PR-I)

Authors
ANDERSON S HILL AF SLAWIN AMZ WHITE AJP WILLIAMS DJ
Citation
S. Anderson et al., BINUCLEAR AROYL AND CARBAMOYL COMPLEXES OF IRON - X-RAY CRYSTAL-STRUCTURES OF [FE-2(MU-SIGMA,SIGMA'-OCR)(2)(CO)(5)(PPH3)] (R = C6H3ME2-2,6,(NPR2)-PR-I), Inorganic chemistry, 37(3), 1998, pp. 594
Citations number
27
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
37
Issue
3
Year of publication
1998
Database
ISI
SICI code
0020-1669(1998)37:3<594:BAACCO>2.0.ZU;2-#
Abstract
The syntheses of two bimetallic complexes [Fe-2(mu:sigma,sigma'-OCR)(2 )(CO)(5)(PPh3)] [R = C6H3Me2-2,6 (1), (NPr2)-Pr-1 (2)] are described, the latter by a variety of routes. A comparison of the structural effe cts of the aroyl and carbamoyl. bridging ligands upon the unsymmetrica lly bridged diiron core follows from crystallographic studies on both complexes.