A novel method is proposed in this study for determining the dissolved
oxygen (DO) diffusion coefficient in industrial wastewaters. The meth
od is based on the principle of measuring the average DO concentration
during the diffusion process. A specially designed experimental appar
atus with an appropriate operating procedure and a mathematical equati
on are necessary in the determination of the DO diffusion coefficient.
The accuracy of the estimated DO diffusion coefficient using the pres
ent method was compared with that reported in the literature and was f
ound to be quite good. Extended test runs were conducted to examine th
e effects of various types of surfactants on the DO diffusion coeffici
ent. Determination of the DO diffusion coefficient in the raw textile
wastewater was demonstrated as a practical example.