SPECTROSCOPIC STUDIES OF EU(III) COMPLEXES WITH IMINODIACETIC AND METHYLIMINODIACETIC ACIDS

Authors
KIM DC YOON SK BAE JH KIM JG KIM YD KANG JG
Citation
Dc. Kim et al., SPECTROSCOPIC STUDIES OF EU(III) COMPLEXES WITH IMINODIACETIC AND METHYLIMINODIACETIC ACIDS, Bulletin of the Korean Chemical Society, 19(1), 1998, pp. 83-86
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Korean Chemical Society → ACNP
ISSN journal
02532964
Volume
19
Issue
1
Year of publication
1998
Pages
83 - 86
Database
ISI
SICI code
0253-2964(1998)19:1<83:SSOECW>2.0.ZU;2-C
Abstract
The luminescence spectra of Eu(III) complexes have been measured as a function of molar metal-to-ligand ratio and pH. The ligands used in th is study are tridentate iminodiacetate ODA) and methyliminodiacetate ( MIDA). The 620 nm emission band, attributed to the D-5(0)-->F-7(2) tra nsition, is monitored to investigate the optimum condition for EuL33- complex formation in aqueous state. In addition, the sensitivity of th e 465 nm absorption band, attributed to the F-7(0)-->D-5(2) transition , to the ligand environment has been also investigated.