Organic monolayers on high-T-c superconductors have allowed for the pr
ecise structural control of composite organic conductor/high-T-c super
conductor assemblies. These hybrid systems display a number of novel e
lectronic and structural properties. This paper discusses the utility
of the monolayer self-assembly procedure for the preparation of both c
onductive polymer and crystalline charge transfer salt layers which ar
e supported directly on top of cuprate superconductor thin film sample
s.