M. Nakagawa et al., ELECTRICAL-PROPERTIES OF IODINE-DOPED MATERIALS COMPRISED OF (PHTHALOCYANINATO)IRON AND AZOPYRIDINES, Synthetic metals, 84(1-3), 1997, pp. 421-422
The preparation and electrical properties of iodine-doped phthalocyani
natoiron polymers {[Fe(Pc)L]I-y}(n) and {[Fe(pc(tb))L]I-y}(n) {Pc=phth
alocyaninato, Pc-tb=tetra-tert-butylphthalocyaninato, L=4,4'-azopyridi
ne (4,4'-APy) and octafluoro-4,4'-azopyridine (4,4'-FAPy)} were invest
igated. The stoichiometry of polymer complexes was determined by TG/DT
A. The iodine-doped {[Fe(Pc)(4,4'-APy)]I-y}(n) complexes were semicond
ucting materials in the range of 10(-4) to 10(-10) S/cm.