Xc. Li et al., A BLUE-LIGHT-EMITTING COPOLYMER WITH CHARGE TRANSPORTING AND PHOTO-CROSS-LINKABLE FUNCTIONAL UNITS, Synthetic metals, 84(1-3), 1997, pp. 437-438
The synthesis of a new poly(methacrylate) copolymer bearing an efficie
nt blue light emitting chromophore, a charge transporting aromatic oxa
diazole and a UV-sensitive crosslinkable unit is reported. The statist
ical copolymer was synthesized via a multi-step route and has been cha
racterised by NMR, FT-IR, and DSC. The copolymer has excellent solutio
n processibility and exhibits strong luminescence. Upon cross-linking
via UV-treatment, the copolymer becomes insoluble, while gaining both
mechanical strength and thermal stability without loss of luminescence
. The structure and properties of this novel copolymer and its applica
tion in light emitting devices are discussed.