IN-SITU FTIR-ATR SPECTROSCOPIC INVESTIGATIONS ON THE POLYMERIZATION PROCESS OF POLY(THIENYLPYRROLE) THIN-FILM ELECTRODES IN NONAQUEOUS SOLUTION

Authors
PING Z NAUER GE
Citation
Z. Ping et Ge. Nauer, IN-SITU FTIR-ATR SPECTROSCOPIC INVESTIGATIONS ON THE POLYMERIZATION PROCESS OF POLY(THIENYLPYRROLE) THIN-FILM ELECTRODES IN NONAQUEOUS SOLUTION, Synthetic metals, 84(1-3), 1997, pp. 577-578
Citations number
6
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
84
Issue
1-3
Year of publication
1997
Pages
577 - 578
Database
ISI
SICI code
0379-6779(1997)84:1-3<577:IFSIOT>2.0.ZU;2-Z
Abstract
Using in situ FTIR-ATR spectroscopy, the electrochemical polymerizatio n process of 2,2'-thienylpvrrole monomer in 0.5 mol cm(-3) LiClO4/acet onitrile (AN) is investigated. According to the structure changes of t he polymerization process recorded by infrared spectra, the polymeriza tion mechanisms of the polymer are discussed in this paper. The monome r and electrolyte absorption on the electrode/electrolyte interface, c hemical and electrochemical polymerization of the monomer are clearly divided at definite potential.