Electron spin susceptibility and ESR linewidth measurements were perfo
rmed to study the electronic state in an unstretched film of Poly(para
phenylene vinylene). Pauli-like susceptibility is observed above 50 K
and Curie-like one below 50 K. Spin carrier diffusion rates are estima
ted and found to be remarkably anisotropic. The present observations a
re consistently understood provided that the charged carriers are in l
ocalized states because of disorder.