SYNTHESIS AND NONLINEAR-OPTICAL PROPERTIES OF A NEW POLYDIACETYLENE DERIVATIVE HAVING SULFUR ATOM DIRECTLY BOUND TO THE MAIN-CHAIN

Authors
MATSUDA H SHIMADA S TAKEDA H MASAKI A VANKEUREN E YAMADA S HAYAMIZU K NAKANISHI F OKADA S NAKANISHI H
Citation
H. Matsuda et al., SYNTHESIS AND NONLINEAR-OPTICAL PROPERTIES OF A NEW POLYDIACETYLENE DERIVATIVE HAVING SULFUR ATOM DIRECTLY BOUND TO THE MAIN-CHAIN, Synthetic metals, 84(1-3), 1997, pp. 909-910
Citations number
10
Categorie Soggetti
Physics, Condensed Matter","Material Science","Polymer Sciences
Journal title
Synthetic metals → ACNP
ISSN journal
03796779
Volume
84
Issue
1-3
Year of publication
1997
Pages
909 - 910
Database
ISI
SICI code
0379-6779(1997)84:1-3<909:SANPOA>2.0.ZU;2-M
Abstract
In order to reduce the band gap of polydiacetylene, a new class of pol ydiacetylene derivative having sulfur atom directly bound to the main chain was synthesized. The solid state polymerization of the new diace tylenes occurs in the manner of the topochemical and topotactic 1,4-ad dition reaction. The evidence of the electron donating effect of the s ulfur atoms of the polydiacetylenes is obvious in the red shift of the absorption maximum and the asymmetrical bond length alternation of th e main chain.