Av. Kasatkin et al., ELECTROCHEMICAL AND CORROSION BEHAVIOR OF TITANIUM WITH VACUUM-DEPOSITED MOLYBDENUM COATING, Protection of metals, 34(1), 1998, pp. 15-18
An increase in titanium corrosion resistance as a result of its diffus
ion molybdenizing from a mixture with an oxide activating agent is sho
wn. The two-phase coating formed is constituted of a low-titanium soli
d solution in molybdenum and rutile, the latter is a product of the mo
lybdenum oxide reduction by titanium. The coating acts as a passivatin
g cathode substantially more effective than compact molybdenum. The co
ating passivates titanium in 10% H2SO4 at 80 degrees C and increases i
ts corrosion resistance by two orders of magnitude.