To recover the ocean water-leaving radiance and derive biophysical par
ameters from observations of space-borne ocean color sensors, the requ
ired uncertainty in the measured top-of-atmosphere radiance is at pres
ent impossible to achieve prior to launch. A methodology and strategy
for achieving the required uncertainty in the post-launch era is prese
nted here. The method consists of combining direct measurements of the
water-leaving radiance, white-cap radiance, and aerosol optical thick
ness made simultaneously with satellite overpasses, with radiative tra
nsfer theory to reduce the calibration uncertainty of the visible band
s with respect to the near-infrared (NIR). This procedure is possible
over the open ocean, where, in the absence of aerosol transported from
land over long distances by the wind, the atmosphere can be very clea
r with most of the aerosol generated by local processes such as breaki
ng waves, for example, the aerosol optical thickness in the visible si
milar to 0.05-0.10. In this case, the radiative transfer process is co
nsiderably simplified and molecular scattering is the dominant atmosph
eric component in the visible. It is shown that such a procedure alone
is sufficient to reduce the calibration uncertainty to required level
s. Further reduction is possible by reducing the uncertainty in the NI
R calibration by measuring sky radiance from island locations (or a sh
ip), and using these to predict the at-sensor radiance. For the most p
art, this NIR calibration is limited by the uncertainty in the calibra
tion of the radiometer used to measure the sky radiance. Finally, the
sensory calibration is maintained by monitoring the actual water-leavi
ng radiance continuously at a single location, where the atmosphere is
sufficiently clear that atmospheric correction introduces only a smal
l error, and directly comparing the true and the sensor-derived water-
leaving radiances. (C) Elsevier Science Inc., 1998.