DISTRIBUTION OF CHARGE IN THE PROCESS OF COATING FE POWDER BY ELECTROLYSIS IN A FLUIDIZED-BED

Citation
M. Galova et al., DISTRIBUTION OF CHARGE IN THE PROCESS OF COATING FE POWDER BY ELECTROLYSIS IN A FLUIDIZED-BED, JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2(1), 1998, pp. 2-6
Citations number
18
Categorie Soggetti
Electrochemistry
ISSN journal
14328488
Volume
2
Issue
1
Year of publication
1998
Pages
2 - 6
Database
ISI
SICI code
1432-8488(1998)2:1<2:DOCITP>2.0.ZU;2-N
Abstract
Theoretical calculations of the amount of Ni that is applied electroly tically in the form of a coating on Fe powder particles in a fluidized bed are based upon the assumption of distribution of charge between t he surface of the solid cathode and the powder particles present in th e working volume of the electrolyte. The experimentally measured data show good agreement with theory. The efficiency of the coating process is rather low because of inhibition of the process by hydroxocomplexe s formed in the course of electrolysis. The inhibition effect becomes more significant in the case of high suspension density, small powder particles, high current density, and prolonged time of electrolysis.