M. Galova et al., DISTRIBUTION OF CHARGE IN THE PROCESS OF COATING FE POWDER BY ELECTROLYSIS IN A FLUIDIZED-BED, JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2(1), 1998, pp. 2-6
Theoretical calculations of the amount of Ni that is applied electroly
tically in the form of a coating on Fe powder particles in a fluidized
bed are based upon the assumption of distribution of charge between t
he surface of the solid cathode and the powder particles present in th
e working volume of the electrolyte. The experimentally measured data
show good agreement with theory. The efficiency of the coating process
is rather low because of inhibition of the process by hydroxocomplexe
s formed in the course of electrolysis. The inhibition effect becomes
more significant in the case of high suspension density, small powder
particles, high current density, and prolonged time of electrolysis.