Based on the study of the positions and heights of the pre-peaks on th
e structure factors of liquid Al-Fe alloys, it is found that the heigh
ts are higher in the region on the phase diagram where nearly all the
intermetallic compounds with higher melting temperature gather, and th
e highest at Fe2Al5; while the positions are smaller, and a minimum at
Fe2Al5. These results reveal the close relationship between the liqui
d structure and the Al-Fe alloy phase diagram. Two types of atomic con
figuration are constructed, and the origin of the pre-peaks is found t
o be the Fe-Fe correlation or the Al-Al correlation, or their mixture
at different compositions.