We report the magnetic field dependence of dielectric constant and mag
netoelectric effect of TmMn2O5 and YbMn2O5 single crystals. An anomalo
us change of magnetoelectric effect occurs at 5 kOe (TmMn2O5) or at 18
kOe (YbMn2O5) at 4.2 K, when an magnetic field is applied along the c
-direction. The anomaly in YbMn2O5 is attributed to a transition betwe
en different magnetic structures. In TmMn2O5 an anomaly was also obser
ved in dielectric constant. We propose a structural transition caused
by a magnetic held.