R. Torre et al., TIME-RESOLVED OPTICAL KERR-EFFECT IN A FRAGILE GLASS-FORMING LIQUID, SALOL, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics, 57(2), 1998, pp. 1912-1920
We report an optical Kerr effect experiment, performed on liquid and s
upercooled liquid salol, in order to test some predictions of the mode
-coupling theory of the liquid-glass transition. We show that this exp
eriment is sensitive mostly to the reorientational motion of the molec
ules and the corresponding correlation function exhibits, above the cr
itical temperature T-C, a von Schweidler relaxation followed by an alp
ha relaxation regime. The critical temperature and the critical expone
nt derived from the analysis of the experiment are in good agreement w
ith the same quantities previously determined, in the frequency domain
, through a depolarized light-scattering experiment, by Li et al. [Phy
s. Rev. B 46, 3343 (1992)]. [S1063-651X(98)04702-3].