Y. Toyozawa, MULTISTEP PHOTOSYNTHESIS OF METASTABLE COMPOUNDS - THE ORIGIN OF LIFEON THE EARTH, Journal of the Physical Society of Japan, 66(12), 1997, pp. 3737-3740
On the basis of the thermodynamic argument of the characteristic featu
re distinguishing the living world from the nonliving, it is postulate
d that the radiation from the sun created living organisms on the eart
h and has been their constant driving force. In view of the fact that
the basic biomolecules have chemical energies of several or more elect
ron volts, significantly higher than the average energy of a photon fr
om the sun, we propose a mechanism of multistep photoexcitations of in
organic material for the photosynthesis of these metastable molecules
which would not exist at ambient temperature. The preference of the ph
otoexcitation against the radiative and nonradiative de-excitation is
ascribed to the suppression of the latter by rapid and large relaxatio
ns (reactions) in intermediate states. An experiment to confirm the me
chanism is proposed in which geological time is reduced to an accessib
le one.