THERMAL STORAGE IN AMMONIUM ALUM AMMONIUM-NITRATE EUTECTIC FOR SOLAR SPACE HEATING APPLICATIONS

Ammonium alum and ammonium nitrate in the weight ratio of 1:1 form a e utectic that melts at 53 degrees C and solidifies at 48 degrees C. The thermophysical properties of this eutectic were measured in detail an d the eutectic was found to have properties desirable for energy stora ge for solar space heating applications. The eutectic was encapsulated in 0.0254-m diameter high-density polyethylene (HDPE) balls and packe d into a cylindrical bed in a scale model for testing its heat transfe r characteristics when exposed to an air flow. Test results indicate t hat the thermal extraction efficiency of the model was 89 percent with an uncertainty of +/- 8.0 percent. The packed bed had a Stanton numbe r value in close agreement with that predicted with an empirical equat ion for sensible heat extraction from the eutectic in the solid phase. This Stanton number was increased by about 74 percent for sensible he at extraction from the eutectic in the liquid phase, a phenomenon not previously reported in the literature.