RAMAN-SPECTROSCOPY OF THE HYDROGEN-BOND IN THE ASSOCIATES H2O-CENTER-DOT-HNO3 AND (HNO3)(2)NO3-CENTER-DOT- EVANS WINDOWS

Authors
POTIER A POTIER J HERZOG MH HERZOG JF
Citation
A. Potier et al., RAMAN-SPECTROSCOPY OF THE HYDROGEN-BOND IN THE ASSOCIATES H2O-CENTER-DOT-HNO3 AND (HNO3)(2)NO3-CENTER-DOT- EVANS WINDOWS, Polish Journal of Chemistry, 72(2), 1998, pp. 292-301
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
72
Issue
2
Year of publication
1998
Pages
292 - 301
Database
ISI
SICI code
0137-5083(1998)72:2<292:ROTHIT>2.0.ZU;2-2
Abstract
The discontinuous shifts of Raman lines with the concentration between 500 and 2600 (-1) in solutions of HNO3-H2O and KNO3-HNO3 show the for mation of the associates cm H2O . HNO3 and (HNO3)2 . NO3-. The study o f the 2000-3600 cm(-1) range enhances the complexity of the OH' spectr a with the occurrence of Evans windows, owing to the formation of hydr ogen bonds in the two associates.