SYNTHESIS, STRUCTURE AND MAGNETISM OF THE OXALATO-BRIDGED CHROMIUM(III) COMPLEX [NBU4N](4)[CR-2(OX)(5)]CENTER-DOT-2CHCL(3)

Authors
MASTERS VM SHARRAD CA BERNHARDT PV GAHAN LR MOUBARAKI B MURRAY KS
Citation
Vm. Masters et al., SYNTHESIS, STRUCTURE AND MAGNETISM OF THE OXALATO-BRIDGED CHROMIUM(III) COMPLEX [NBU4N](4)[CR-2(OX)(5)]CENTER-DOT-2CHCL(3), Journal of the Chemical Society. Dalton transactions, (3), 1998, pp. 413-416
Citations number
50
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
3
Year of publication
1998
Pages
413 - 416
Database
ISI
SICI code
0300-9246(1998):3<413:SSAMOT>2.0.ZU;2-6
Abstract
The binuclear complex [NBu4n](4)[Cr-2(ox)(5)]. 2CHCl(3) has been prepa red by an ion-exchange procedure employing Dowex 50WX2 cation-exchange resin in the n-butylammonium form and potassium tris(oxalato)chromate (III). The dimeric complex was characterised by a crystal structure de termination: monoclinic, space group C2/c, a = 29.241(7), b = 15.192(2 ), c = 22.026(5) Angstrom, beta = 94.07(1)degrees, Z = 4. The magnetic susceptibility (300-4.2 K) indicated that the chromium(III) sites wer e antiferromagnetically coupled (J = -3.1 cm(-1)).