A HORNER-WADSWORTH-EMMONS APPROACH TO [(S)R]-4-SUBSTITUTED 1-P-TOLYLSULFINYL-1,3-DIENES

Authors
ARCE E CARRENO MC CID MB RUANO JLG
Citation
E. Arce et al., A HORNER-WADSWORTH-EMMONS APPROACH TO [(S)R]-4-SUBSTITUTED 1-P-TOLYLSULFINYL-1,3-DIENES, Tetrahedron : asymmetry, 6(7), 1995, pp. 1757-1764
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
6
Issue
7
Year of publication
1995
Pages
1757 - 1764
Database
ISI
SICI code
0957-4166(1995)6:7<1757:AHAT[1>2.0.ZU;2-K
Abstract
[(S)R,1E,3E]-4-p-Tolylsulfinyl-1-X-1,3-butadienes 1 (X = CO(2)Me, CN, PO(OEt)(2), SO2 Ph, SEt) are synthesized from a common starting materi al, [(S)R]-3-p-tolylsulfinyl-2-propenal 2, through a Horner-Wadsworth- Emmons reaction with the phosphonate (XCH(2)PO(OEt)(2)). The synthesis of 2 is also described.