SYNTHESIS AND CRYSTAL-STRUCTURE OF PENTAK IS(DIMETHYLSULFOXIDE)-OXO-TITANIUM(IV) CHLORIDE

Authors
ENDERS M RUDOLPH R PRITZKOW H
Citation
M. Enders et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF PENTAK IS(DIMETHYLSULFOXIDE)-OXO-TITANIUM(IV) CHLORIDE, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 52(4), 1997, pp. 496-499
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
52
Issue
4
Year of publication
1997
Pages
496 - 499
Database
ISI
SICI code
0932-0776(1997)52:4<496:SACOPI>2.0.ZU;2-S
Abstract
Pentakis(dimethylsulfoxide)-oxo-titanium chloride is obtained by react ion of titanium tetrachloride with a stoichiometric amount of water in dimethylsulfoxide. A single crystal structure determination (P (1) ov er bar, a = 9.564(6), b = 10.504(7), c = 12.510(8) Angstrom, a = 70.21 (5), beta = 83.48(5), gamma = 89.82(5)degrees, V = 1174 Angstrom(3), Z = 2) shows a dicationic titanium(IV) complex with five dimethylsulfox ide ligands and one oxygen atom. The two chlorine anions are not bonde d to the complex cation. The TiO6-fragment is a distorted octahedron, where five of the six oxygen atoms belong to the coordinated dimethyls ulfoxide molecules.