A review of previous derivations of particle collision rates in turbul
ent fluid flow shows that these are applicable only to limited cases.
A more general derivation is given, taking into account the effects of
the inertia of the particles and the difference in densities of the f
luid and the particles. A universal solution for the relative velocity
of two particles due to turbulent accelerations in a gaseous or liqui
d system is presented. In gaseous systems the acceleration mechanism b
ecomes predominant at particle sizes far below the Kolmogorov microsca
le of turbulence. In liquid systems, the particle inertial and added m
ass effects become important above the Kolmogorov microscale. Here the
particle collision rate cannot be estimated from the fluid turbulent
velocity fluctuations only.