Conformality limitations and film composition variations inside featur
es for films deposited at low pressures are explained using examples o
f studies which combine transport and reaction simulations of depositi
on processes and carefully designed experimental work. In the first ex
ample, the use of film profile information to decide between two kinet
ic models for the deposition of SiO2 from TEOS is described. In the se
cond example, composition profiles in sputter deposited Ti-W are expla
ined in terms of titanium re-emission. Combined simulation and experim
ental studies of film profiles and composition profiles in features is
a valuable tool in efforts to arrive at useful kinetic and transport
models.