A recently developed magnetic resonance imaging (MRI) technique is use
d to study the concrete freeze/thaw process. Ice formation is spatiall
y resolved in a nondestructive manner as changes in the MRI signal int
ensity are observed. The phase transition temperatures are in agreemen
t with published differential scanning calorimetry thermograms. The co
ncrete samples were air dried for varying times. The imaging of both s
aturated and non-saturated specimens demonstrates the ability to monit
or non-adsorbed water in a range of pore sizes. The freeze/thaw thermo
dynamic behaviour was found to depend on water content and sample hist
ory. (C) 1998 Elsevier Science Ltd.