This is the thirteenth annual review published in JAAS of the applicat
ions of atomic spectroscopy to the chemical analysis of environmental
samples. The format used continues to be similar to that of previous y
ears, highlighting the main features of this particular subject. Devel
opments in instrumentation are not essentially a feature of this updat
e, and so the emphasis is mainly with the establishment of reliable an
d robust methods of environmental analysis. The update does; however,
focus on the areas of sampling, sample preparation and sample introduc
tion in atomic spectroscopy. The most popular areas for development in
sample preparation continues to be dissolution/decomposition, separat
ion and preconcentration, and solvent extraction, with the emphasis on
the establishment of robust and valid methodology. The motives for th
is approach are usually being led by the necessity to develop simpler,
low cost and safe methods. The importance of trace element determinat
ion in environmental analysis reflects the need of industry, governmen
t bodies and other interested groups to obtain reliable data as to the
level of pollutants in the environment.