SUCCESSIVE O-C O-H AND SP(3) C-H BOND ACTIVATION OF ORTHO SUBSTITUENTS IN ALLYL PHENYL ETHERS AND PHENOLS BY A RUTHENIUM(0) COMPLEX/

Authors
HIRANO M KURATA N MARUMO T KOMIYA S
Citation
M. Hirano et al., SUCCESSIVE O-C O-H AND SP(3) C-H BOND ACTIVATION OF ORTHO SUBSTITUENTS IN ALLYL PHENYL ETHERS AND PHENOLS BY A RUTHENIUM(0) COMPLEX/, Organometallics, 17(4), 1998, pp. 501-503
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
4
Year of publication
1998
Pages
501 - 503
Database
ISI
SICI code
0276-7333(1998)17:4<501:SOOASC>2.0.ZU;2-W
Abstract
Successive O-C and sp(3) C-H bond activation. occurs in the reaction o f Ru(COD)(COT) (1) [PMe3 with allyl 2,6-xylyl ether to give Ru[OC6H3(o -CH2)(o'-Me)](PMe3)(4) (4). Alternatively, 4 can be obtained by O-H an d sp(3) C-H bond activation in 2,6-xylenol by 1/PMe3. In both cases, a n eta(3)-allyl fragment could be responsible for the sp(3) C-H bond ac tivation.