SYNTHESIS, CRYSTAL-STRUCTURE, AND REACTIVITY OF (5,10,15,20-TETRAPHENYLPORPHYRINATO)RUTHENIUM(II) (DIETHOXYCARBONYL)CARBENE METHANOL

Authors
GALARDON E LEMAUX P TOUPET L SIMONNEAUX G
Citation
E. Galardon et al., SYNTHESIS, CRYSTAL-STRUCTURE, AND REACTIVITY OF (5,10,15,20-TETRAPHENYLPORPHYRINATO)RUTHENIUM(II) (DIETHOXYCARBONYL)CARBENE METHANOL, Organometallics, 17(4), 1998, pp. 565-569
Citations number
50
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
17
Issue
4
Year of publication
1998
Pages
565 - 569
Database
ISI
SICI code
0276-7333(1998)17:4<565:SCARO(>2.0.ZU;2-F
Abstract
The new (porphyrin)ruthenium(II) carbene complex 1 has been prepared b y treating (TPP)-Ru(CO)[EtOH] with excess diethyl diazomalonate. The g ood Stability of this complex allowed us to determine its structure by single-crystal X-ray diffraction. The reactivity of 1 toward various axial ligands (CO, pyridine, triphenylphosphine) is also discussed, as well as its ability, from ethyl diazoacetate, to catalyze the couplin g formation of olefins and the cyclopropanation of styrene.