NEW (2,4,6-TRIISOPROPYLPHENYL) HYDROHALOGERMANES, HALOHALOGERMANES AND HYDROHALOGERMANES

Citation
Ma. Chaubon et al., NEW (2,4,6-TRIISOPROPYLPHENYL) HYDROHALOGERMANES, HALOHALOGERMANES AND HYDROHALOGERMANES, Synthesis and reactivity in inorganic and metal-organic chemistry, 27(4), 1997, pp. 519-533
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
00945714
Volume
27
Issue
4
Year of publication
1997
Pages
519 - 533
Database
ISI
SICI code
0094-5714(1997)27:4<519:N(HHA>2.0.ZU;2-Y
Abstract
New hydro-, halo- and hydrohalogermanes of the types IsGeH(3-n)Cl(n) ( n = 0, 1, 3, Is = 2,4,6-triisopropylphenyl) and Is(R)GeH2-nXn (n = 0 o r 2, X = Cl, F), potential precursors of stable, low-coordinated speci es of germanium, have been synthesized. All of them are substituted by at least one bulky 2,4,6-triisopropylphenyl group, R being a second I s group, a mesityl, a pentamethylcyclopentadienyl or a fluorenyl group .