Ma. Chaubon et al., NEW (2,4,6-TRIISOPROPYLPHENYL) HYDROHALOGERMANES, HALOHALOGERMANES AND HYDROHALOGERMANES, Synthesis and reactivity in inorganic and metal-organic chemistry, 27(4), 1997, pp. 519-533
New hydro-, halo- and hydrohalogermanes of the types IsGeH(3-n)Cl(n) (
n = 0, 1, 3, Is = 2,4,6-triisopropylphenyl) and Is(R)GeH2-nXn (n = 0 o
r 2, X = Cl, F), potential precursors of stable, low-coordinated speci
es of germanium, have been synthesized. All of them are substituted by
at least one bulky 2,4,6-triisopropylphenyl group, R being a second I
s group, a mesityl, a pentamethylcyclopentadienyl or a fluorenyl group
.