L. Chirchi et al., STUDY OF 2-NITROPHENOL PHOTOASSISTED DEGR ADATION IN AQUEOUS-MEDIUM CATALYZED BY AL-CU MIXED PILLARED CLAYS, Journal de chimie physique et de physico-chimie biologique, 94(11-12), 1997, pp. 1869-1882
The results reported concern an investigation of the photoassisted deg
radation of nitrophenol in aqueous medium catalysed by copper adsorbed
on aluminium pillared clay. Polarography, gas chromatography and UV-v
is. were used to obtain informations on the nature of intermediate spe
cies formed during reaction. The degradation of nitrophenol leads to C
O2 (mineralisation), H-2, NO3- and NO2-, the rates for the obseved pro
cesses were shown to be a fonction of amount and nature of the catalys
t, pH, dissolved O-2 and light activation.